When I Said I Do: by Clint Black and Lisa Hartman Black - This romantic duet was released in 1999 and showcases the chemistry between real-life couple Clint.
Islands in the Stream: by Dolly Parton and Kenny Rogers - This classic duet was released in 1983 and is still considered one of the best country duets of all time.
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The Gambler: by Kenny Rogers and Dolly Parton - Another iconic duet between these two legends, "The Gambler" was released in 1978.
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Jackson: by Johnny Cash and June Carter Cash - This classic duet from 1967 tells the story of a couple named Jackson and Anna Lee.
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You're the Reason God Made Oklahoma: by David Frizzell and Shelly West - This 1981 duet is a classic example of the country love song.
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It's Your Love: by Tim McGraw and Faith Hill - This romantic ballad was released in 1997 and became a huge hit for the power couple.
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Don't You Wanna Stay: by Jason Aldean and Kelly Clarkson - This duet was a big hit in 2010 and showcases the vocal range of both Aldean and Clarkson.
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Whiskey Lullaby: by Brad Paisley and Alison Krauss - This emotional ballad tells the story of a failed relationship and the drinking that follows.
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Louisiana Woman, Mississippi Man: by Conway Twitty and Loretta Lynn - This duet from 1973 tells the story of a couple from different states who fall.
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I Told You So: by Carrie Underwood and Randy Travis - Originally a hit for Randy Travis in 1988, this duet version with Carrie Underwood was released in 2009.