These on-screen couples had absolutely no chemistry
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Barney Stinson and Robin Scherbatsky - Played by Neil Patrick and Cobie Smulders, this is likely the couple with the least chemistry in 'How I Met Your Mother.'
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Belle and Beast - 'Beauty and the Beast' (2017) is a beautiful story, but less beautiful is the on-screen chemistry between Emma Watson and Dan Stevens.
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Lady Sarah Ashley and Drover - Australian actors Nicole Kidman and Hugh Jackman aren't the dream couple we'd like them to be in 'Australia' (2008).
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Abigail "Abby" Richter and Mike Chadway - Katherine Heigl and Gerard Butler wouldn't make a great couple. Just watch 'The Ugly Truth' (2009) if you don't believe us.
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Andrea "Andy" Sachs and Nate Cooper- Anne Hathaway and Adrian Grenier play this couple in 'The Devil Wears Prada' (2006), but it's a couple that viewers aren't rooting for.
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Longfellow Deeds and Babe Bennett - Winona Ryder comes next as one of Adam Sandler's most uncomfortable leading ladies, for her role in 'Mr. Deeds' (2002).
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David Aames and Julianna "Julie" Gianni-Although things got better in 'Knight and Day' (2010), Tom Cruise and Cameron Diaz had very little chemistry in 'Vanilla Sky' (2001).
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Jay Gatsby and Daisy Buchanan - Carey Mulligan and Leonardo DiCaprio looked cute in 'The Great Gatsby' (2013), but she's no Kate Winslet.
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Dave and Ronnie - Vince Vaughn and Malin Akerman played a troubled couple in 'Couples Retreat' (2009), so the lack of chemistry was probably intentional for the roles.
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Hal Larson and Rosemary "Rosie" Shanahan - There's just something off about Jack Black and Gwyneth Paltrow's characters in 'Shallow Hal' (2000).