Nickel‐Catalyzed Tandem Ring Contraction of TEMPO and C‐N Bond Transamination of Enaminones toward Amino Diversity of Enaminones

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The reactions of N,N -substituted enaminones with TEMPO top to the synthesis of 2,2-dimethyl pyrrolidine functionalized new enaminones have been set up by Ni(II) catalysis. Interesting ring contraction on TEMPO as effectively as the enaminone C-N bond amination deliver new device for generating molecular range of enaminones in the amino team fragment.

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